Diaqua-1κO,3κO-di-μ-cyanido-1:2κ2 N:C;2:3κ2 C:N-dicyanido-2κ2 N-bis{4,4′-dibromo-2,2′-[propane-1,2-diylbis(nitrilomethylidyne)]diphenolato}-1κ4 O,N,N′,O′;3κ4 O,N,N′,O′-1,3-dimanganese(III)-2-nickel(II)
نویسندگان
چکیده
In the title compound, [Mn(2)Ni(C(17)H(14)Br(2)N(2)O(2))(2)(CN)(4)(H(2)O)(2)] or [{Mn(C(17)H(14)Br(2)N(2)O(2))(H(2)O)}(2)(μ-CN)(2){Ni(CN)(2)}], each Mn(III) atom is chelated by a Schiff base ligand via two N and two O atoms and is additionally coordinated by a water mol-ecule to give a slightly distorted octa-hedral geometry. Two such Mn(III) ions are linked by a square-planar Ni(CN)(4) unit, which lies on an inversion centre. A two-dimensional network is formed by O-H⋯O and O-H⋯N hydrogen bonds.
منابع مشابه
Diaqua-1κO,3κO-di-μ-cyanido-1:2κ2 N:C;2:3κ2 C:N-dicyanido-2κ2 C-bis{4,4′-dibromo-2,2′-[propane-1,2-diylbis(nitrilomethylidyne)]diphenolato}-1κ4 O,N,N′,O′;3κ4 O,N,N′,O′-1,3-diiron(III)-2-nickel(II)
The title compound, [Fe(2)Ni(C(17)H(14)Br(2)N(2)O(2))(2)(CN)(4)(H(2)O)(2)] or [{Fe(C(17)H(14)Br(2)N(2)O(2))(H(2)O)}(2)(μ-CN)(2){Ni(CN)(2)}], is iso-structural with its Mn(III)-containing analogue. Each Fe(III) atom is chelated by a Schiff base ligand via two N and two O atoms and is additionally coordinated by a water mol-ecule, forming a slightly distorted octa-hedral geometry. The two Fe(III)...
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008